恕我直言，没人能用 py requests 库下载这张照片

import requests

if __name__ == '__main__':

    print(requests.get(
        "https://img.23jj.com/image/32/3270/0_236.jpg",
        headers={
            "User-Agent": "Mozilla/5.0 (Macintosh; Intel Mac OS X 10_15_7) AppleWebKit/537.36 (KHTML, like Gecko) Chrome/92.0.4515.131 Safari/537.36",
            "Host": "https://www.23jj.com"
        }).content)