难以理解为什么MySQL不接受我的查询?

Okay, so I'm currently using mysqli_real_escape_string to escape my SQL queries before sending them to MySQL via PHP. Yet, for some reason my queries aren't processing, and when I outputted the MySQL query and pasted it in to PHPMyAdmin, it gave the following error:

#1064 - You have an error in your SQL syntax; check the manual that corresponds to your MySQL server version for the right syntax to use near 'WHERE ind={A$RTkAIqah0J1N$Fqymnud9s5PwnWw2wC.Y02oDo4H3W8QJPoJ$6$KK8UearuUCDH$FQg' at line 1

Now, the following is my query:

INSERT INTO `db`.table(`colheader`) VALUES ('{\"hey\":[\"Hello world\",\"7\\/9\\/2013\"]}') WHERE ind='$6$RTkAIqah0J1N$Fqymnud9s5PwnWw2wC.Y02oDo4H3W8QJPoJ$6$KK8UearuUCDH$FQgSnLHIlkBOtDTzu9AuZIZTr6GS4Rzr.iW11041994'

Now, I know that the string assigned to 'ind' has some issues, but I tried putting a slash before every period and every dollar sign and it still doesn't work. I tried putting the whole thing in double quotes, even brackets. Nothing. Could anyone point out what I'm clearly missing? I've looked at the documentation and can't seem to find anything. Thank you in advance!!

WHERE serves to filter which records will be affected or retrieved by your query, and INSERT servers to append a whole new record to a table.

An INSERT can never affect existing records, therefore its nonsense to have a WHERE clause. INSERT does not support WHERE.

If you are trying to edit the value of a field on an existing record, use UPDATE instead.

Take a look at the MySQL Reference Manual for details about its usage.

if your trying to make an update to the specified index use

UPDATE `db`.table SET `colheader` = '{\"hey\":[\"Hello world\",\"7\\/9\\/2013\"]}' WHERE ind='$6$RTkAIqah0J1N$Fqymnud9s5PwnWw2wC.Y02oDo4H3W8QJPoJ$6$KK8UearuUCDH$FQgSnLHIlkBOtDTzu9AuZIZTr6GS4Rzr.iW11041994'