会等到子程序完成执行吗?

I have such function:

func TestDefer(lock sync.RWMutex, wait time.Duration) {

    lock.Lock()
    defer lock.Unlock()

    // start goroutine 
    go func() {
        time.Sleep(wait)
    }()
}

I am eager to know when lock.Unlock() will be executed? Is it synchronized with subroutine go func() ? Will it be waiting until it finishes?

No. Defer will not wait for your go routine to finish. IF you want to do that, wait till the go routine is done executing using sync.WaitGroup.

func TestDefer(lock sync.RWMutex, wait time.Duration) {
    wg := new(sync.WaitGroup)
    lock.Lock()
    defer lock.Unlock()

    wg.Add(1)
    // start goroutine 
    go func() {
        defer wg.Done()
        time.Sleep(wait)
    }()
    wg.Wait()
}

No, as soon as the go statement finishes its execution (that is, the Go runtime creates a new goroutine and puts it on some run queue), the execution of the function continues, and since the function's body ends there, the functions deferred in it will run.

Synchronization between goroutines only ever happens explicitly—by means of channel operations of using primitives from the packages of the sync hierarchy.